It also depends on the material your structure is made of.
If brick, it will darken over the years due to soot, smoke, exhaust in the air. The effect will be very even all over the structure, so you would probably just use a darker paint to begin with.
If wood, the ravages of time will attack the paint. It will be peeling, or completely worn away, leaving darkend wood underneath. Obviously, this would not be even, and the greatest effect will be on the "weather side" of the building (around here that's west), and in areas where water would pool. Brush painting works best here - although some people use a resist (like rubber cement or airbrush masking) in spots here and there before they paint, then peel off the resist leaving bare wood. But the bare wood should also be weathered. Alcohol/india ink stain works perfectly.
If metal, the effects of time and weathering are rust. Again, you have to think about where water will pool, as those are the areas that get the most damage. Also, streaks of rusty water run off the metal, usually onto concrete, or whatever you have supporting the metal. This is where weathering powders, and washes come in. First add the powder, then with a fine brush dipped in alcohol, allow the alcohol to run down the sides, following gravity.
A gas station could easily have all of these materials present, so you should probably use a combination of techniques.
Where airbrushing comes in super handy is around the bases of buildings. Dust and dirt get kicked up from the ground by wind and rain, and leave a thin coating at the very bottom.
Hope this helps.
Val